On a formulation for anisotropic elastoplasticity at finite strains invariant with respect to the intermediate configuration

The paper is concerned with a formulation of anisotropic finite strain inelasticity based on the multiplicative decomposition of the deformation gradient F=F_eF_p. A major feature of the theory is its invariance with respect to rotations superimposed on the inelastic part of the deformation gradient. The paper motivates and shows how such an invariance can be achieved. At the heart of the formulation is the mixed-variant transformation of the structural tensor, defined as the tensor product of the privileged directions of the material as given in a reference configuration, under the action of F_p. Issues related to the plastic material spin are discussed in detail. It is shown that, in contrast to the isotropic case, any flow function formulated purely in terms of stress quantities, necessarily exhibits a non-vanishing plastic material spin. The possible construction of spin-free rates is discussed as well, where it is shown that the flow rule must then depend not only on the stress but on the strain as well.     

Damage characteristics and surface description of near-wall materials subjected to ultrasonic cavitation

For the analysis of ultrasonic cavitation erosion on the surface of materials, the ultrasonic cavitation erosion experiments for AlCu4Mg1 and Ti6Al4V were carried out, and the changes of surface topography, surface roughness, and Vickers hardness were explored. Cavitation pits gradually expand and deepen with the increase of experiment time, and Ti6Al4V is more difficult to erode by cavitation than AlCu4Mg1. After experiments, the cavitation damage characteristics such as the single pit, the rainbow ring area, the fisheye pit, and some small pits were observed, which can be considered to be induced by a single micro-jet impact, ablation effect caused by the high temperature, micro-jet impingement with a sharp angle, and multibeam micro-jets coupling impact or negative pressure in the local area produced by micro-jet impact, respectively. The surface roughness and Vickers hardness of the material increase slowly after rapid growth at different points in time as the experiment time increases. With the increase of the ultrasonic amplitude, both of them first increase and then decrease after the ultrasonic amplitude is greater than 10.8 μm. The increases in surface roughness and Vickers hardness tend to decrease as the viscosity coefficient increases. Ultrasonic cavitation can cause submicron surface roughness and increase surface hardness by 20.36%, so it can be used as a surface treatment method.     

On the definition of cavitation intensity

Cavitation intensity has already been used to character the activity or strength of cavitation, and several methods are developed to measure the cavitation intensity. However, the previous definitions of cavitation intensity are often either vague or biased. In this paper, from the point of view of energy, the authors proposed a generalized definition of cavitation intensity, derived an approximate formula to calculate the cavitation intensity and discussed its measure method.     

Degradation of methylparaben by sonocatalysis using a Co–Fe magnetic carbon xerogel

The degradation of methylparaben (MP) through 20 kHz ultrasound coupled with a bimetallic Co-Fe carbon xerogel (CX/CoFe) was investigated in this work. Experiments were performed at actual power densities of 25 and 52 W/L, catalyst loadings of 12.5 and 25 mg/L, MP concentrations between 1 and 4.2 mg/L and initial pH values between 3 and 10 in ultrapure water (UPW). Matrix effects were studied in bottled water (BW) and secondary treated wastewater (WW), as well as in UPW spiked with bicarbonate, chloride or humic acid. The pseudo–first order kinetics of MP degradation increase with power and catalyst loading and decrease with MP concentration and matrix complexity; moreover, the reaction is also favored at near–neutral conditions and in the presence of dissolved oxygen. The contribution of the catalyst is synergistic to the sonochemical degradation of MP and the extent of synergy is quantified to be >45%. This effect was ascribed to the ability of CX/CoFe to catalyze the dissociation of hydrogen peroxide, formed through water sonolysis, to hydroxyl radicals. Experiments in UPW spiked with an excess of tert-butanol (radical scavenger), sodium dodecyl sulfate or sodium acetate (surfactants) led to substantially decreased rates (i.e. by about 8 times), thus implying that the liquid bulk and the gas-liquid interface are major reaction sites. The stability of CX/CoFe was shown by performing reusability cycles employing magnetic separation of the catalyst after the treatment stage. It was found that the CX/CoFe catalyst can be reused in up to four successive cycles without noteworthy variation of the overall performance of the sonocatalytic process.     

Cavitation onset caused by a dynamic pressure wave in liquid pipelines

When liquids flow in the pipelines, the onset of cavitation can be characterized by a variant of the Euler number known as the cavitation number (CN), which is based on the velocity and denoted by C in this paper. Conventionally, cavitation is considered to be induced when C ~ 1. However, experimental observations and several pipe bursts indicate that the CN may incorrectly predict the onset of cavitation. For example, when leakage occurs in the pipeline or a valve in the pipeline is opened, the resultant pressure loss generates a dynamic pressure wave with a small amplitude, which may lead to bubble formation, even though C ~ 1 is not satisfied. Hence, this paper proposes another CN based on the amplitude of the generated dynamic pressure wave, rather than the velocity, for ascertaining the onset of cavitation. The validity of the proposed CN was verified through experiments and a case study. The results indicated that the proposed CN can be effectively used for cavitation prediction induced by pressure fluctuations and for investigating phenomena such as pressure fluctuation, leakage, and corrosion in liquid pipelines, tanks, and pressure vessels, as well as the safety design of liquefied natural gas tanks and tankers.     

A study on anomalous yield drop behaviour in modified beta titanium alloys

ABSTRACT

The yield drop phenomenon observed in the Ti–15V-3Al–3Sn-3Cr (Ti–15–3) beta-titanium alloy and its anomalous behaviour in the boron and carbon added Ti–15–3 alloys have been studied. While the base and the carbon containing alloys exhibit yield drop, the boron containing alloy with smaller grain size than base alloy does not appear to show this phenomenon. Tensile tests were interrupted at different stress levels followed by analyses of slip lines and sub-structural characteristics using scanning and transmission electron microscopes to understand this anomalous yield point phenomenon. Infrared thermal imaging technique was used to map the strain localisation and the spatiotemporal evolution of deformation along the gauge length of the specimens during the tensile tests. Deformation in these alloys initiates only in a few grains. Pile-up of dislocations in these grains subsequently triggers the formation of dislocations in other grains and their rapid multiplications. The spreading of deformation by the generation of dislocations from pile up dislocations in one grain to neighbouring un-deformed grains and their rapid multiplication to new regions influence the yield drop phenomenon and its characteristics. It is shown in this study that microscopic instability in the grain level is a necessary, but not the sufficient condition for the manifestation of macroscopic instability during tensile deformation in polycrystalline materials. The presence of boride particles at grain boundaries restricts the slip transfer across the grains as well as the spreading of deformation to new regions, which causes the suppression of yield drop in the boron containing alloy.     

Visualisation and les simulation of cavitation cloud formation and collapse in an axisymmetric geometry

Visualisation and Large Eddy Simulations (LES) of cavitation inside the apparatus previously developed by Franc (2011) for surface erosion acceleration tests and material response monitoring are presented. The experimental flow configuration is a steady-state closed loop flow circuit where pressurised water, flowing through a cylindrical feed nozzle, is forced to turn 90° and then, move radially between two flat plates towards the exit of the device. High speed images show that cavitation is forming at the round exit of the feed nozzle. The cavitation cloud then grows in the radial direction until it reaches a maximum distance where it collapses. Due to the complexity of the flow field, direct observation of the flow structures was not possible, however vortex shedding is inferred from relevant simulations performed for the same conditions. Despite the axisymmetric geometry utilized, instantaneous pictures of cavitation indicate variations in the circumferential direction. Image post-processing has been used to characterize in more detail the phenomenon. In particular, the mean cavitation appearance and the cavity length have been estimated, showing good correlation with the erosion zone. This also coincides with the locations of the maximum values of the standard deviation of cavitation presence. The dominant frequency of the ‘large-scale’ cavitation clouds has been estimated through FFT. Cloud collapse frequencies vary almost linearly between 200 and 2000 Hz as function of the cavitation number and the downstream pressure. It seems that the increase of the Reynolds number leads to a reduction of the collapse frequency; it is believed that this effect is due to the agglomeration of vortex cavities, which causes a decrease of the apparent frequency. The results presented here can be utilized for validation of relevant cavitation erosion models which are currently under development.     

On the possibility of shock-induced cavitation in submerged cylindrical shell systems

A circular cylindrical shell loaded by one or two fluids and responding to an external shock wave is analyzed in the context of the possible inception of shock-induced cavitation. Several scenarios of fluid contact are considered including a submerged evacuated shell and a submerged fluid-filled shell for three different combinations of the parameters of the internal and external fluids. A semi-analytical shell-shock interaction model is employed in order to predict the regions of the fluids where cavitation is likely to occur, and the respective cavitation development is hypothesized about. The most interesting and practically important finding is that when fluid is present both inside and outside the shell, there exist conditions when cavitation is expected to occur in both the internal and external fluid, resulting in a particularly complex and violent structural re-loading occurring upon the collapse of the respective cavitation regions. The inception of cavitation in the internal fluid alone and in the external fluid alone is also possible. The findings are summarized in a manner that is suitable for use at the pre-design stage as a guide for preliminary assessment of the possibility of shock-induced cavitation in fluid-interacting industrial systems.